Search results for "ultraviolet fluorescence"

showing 2 items of 2 documents

Short hydrogen bonds enhance nonaromatic protein-related fluorescence

2021

Significance Intrinsic fluorescence of nonaromatic amino acids is a puzzling phenomenon with an enormous potential in biophotonic applications. The physical origins of this effect, however, remain elusive. Herein, we demonstrate how specific hydrogen bond networks can modulate fluorescence. We highlight the key role played by short hydrogen bonds, present in the protein structure, on the ensuing fluorescence. We provide detailed experimental and molecular evidence to explain these unusual nonaromatic optical properties. Our findings should benefit the design of novel optically active biomaterials for applications in biosensing and imaging.

Chemical transformationOptics and PhotonicsGlutamineIntrinsic fluorescenceMolecular Dynamics SimulationPhotochemistryFluorescenceAb initio molecular dynamicsAmmoniaHumansSingle amino acidshort hydrogen bondDensity Functional TheoryMultidisciplinaryHydrogen bondChemistryintrinsic fluorescenceultraviolet fluorescenceHydrogen BondingConical intersectionFluorescenceBiophysics and Computational BiologyExcited statePhysical Sciences408PeptidesProceedings of the National Academy of Sciences of the United States of America
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Integrated three-dimensional models for noninvasive monitoring and valorization of the Morgantina silver treasure (Sicily)

2016

The Morgantina silver treasure belonging to the Archaeological Museum of Aidone (Sicily) was involved in a three-dimensional (3-D) survey and diagnostics campaign for monitoring the collection over time in anticipation of their temporary transfer to the Metropolitan Museum of Art in New York for a period of 4 years. Using a multidisciplinary approach, a scientific and methodological protocol based on noninvasive techniques to achieve a complete and integrated knowledge of the precious items and their conservation state, as well as to increase their valorization, has been developed. All acquired data, i.e., 3-D models, ultraviolet fluorescence, x-ray images, and chemical information, will be…

Engineering3d scanningnoninvasive diagnostic01 natural sciencessemantic annotationthree-dimensional scanning; reverse modeling; noninvasive diagnostics; semantic annotations; web-oriented platformweb-oriented platform0601 history and archaeologyElectrical and Electronic EngineeringThree dimensional scanningUltraviolet radiationSettore L-ART/04 - Museologia E Critica Artistica E Del Restauroreverse modeling060102 archaeologySettore INF/01 - Informaticabusiness.industry010401 analytical chemistry3d image processing06 humanities and the artsData scienceAtomic and Molecular Physics and Optics0104 chemical sciencesComputer Science ApplicationsSettore ICAR/17 - DisegnoTreasurethree-dimensional scanningbusinessTelecommunicationsUltraviolet fluorescenceReverse modelingSettore MED/36 - Diagnostica Per Immagini E RadioterapiaThree dimensional model
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